(E)-2-[(2-Hydroxyethyl)iminiomethyl]-6-methoxyphenolate
نویسندگان
چکیده
The title Schiff base compound, C(10)H(13)NO(3), obtained by the reaction of 2-hydr-oxy-3-methoxy-benzaldehyde and 2-amino-ethanol in methanol solution, crystallizes in a zwitterionic form, in which the mol-ecule adopts a trans configuration about the central C=N bond. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal structure, mol-ecules are linked into chains by inter-molecular O-H⋯O hydrogen bonding.
منابع مشابه
(E)-4-Allyl-2-[(2-hydroxyphenyl)iminiomethyl]-6-methoxyphenolate
The title compound, C(17)H(17)NO(3), crystallizes in a zwitterionic form with cationic iminium and anionic enolate groups. The zwitterion exists in a trans configuration about the C=N bond. The dihedral angle between the two benzene rings is 13.42 (7)°. The meth-oxy group is almost coplanar [C-O-C-C = 2.1 (2)°] with the attached ring whereas the allyl unit is oriented at a dihedral angle of 67....
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